Wu P. Micro-Mesoporous Metallosilicates. Synthesis, Characterization,...2024

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Wu P. Micro-Mesoporous Metallosilicates. Synthesis, Characterization,...2024

Textbook in PDF format Up-to-date and in-depth text bridging the technology gap between fundamental research and industry-scale applications of porous materials for catalysis Micro-Mesoporous Metallosilicates: Synthesis, Characterization, and Catalytic Applications comprehensively introduces the chemistry and catalytic technologies of metallosilicates, an important family of microporous crystalline zeolite and heteroatom-containing mesoporous materials, with a primary focus on design synthesis, characterization, theoretical studies, and catalytic applications of titanosilicates, tin-silicates, germanosilicates and Ti-mesosilica, and more. The text covers recent advances in the synthesis of titanosilicates, including hydrothermal synthesis, dry-gel conversion, fluoride-assisted synthesis, and post-synthesis methods, along with the synthesis of metallosilicates with two-dimensional lamellar structures and their structural modifications as well as applications in selective oxidation reactions. The text also discusses synthesis of germanosilicates with specially designed organic structure-directing agents, synthesis and catalytic applications of heteroatom-containing mesoporous silica, and dendritic mesoporous silica nanoparticles with unique wrinkled center-radial structures. Overall, every important porous metallosilicate and its synthesis, characterization, pore engineering, catalytic application, and industrial technique and process are covered. Specific sample topics discussed in Micro-Mesoporous Metallosilicates include: Chemical post-modifications of titanosilicates, in terms of the effects on transfer, adsorption/desorption, and surface reactions. X-Ray based techniques, ultraviolet-visible-near infrared spectroscopy, Raman spectroscopy, and solid-state NMR spectroscopy. Theoretical calculation as an effective tool and supplement to understand the catalytic active center, structural character, and Brønsted/Lewis acidity. Titanosilicates in the liquid-phase epoxidation reaction of propylene and propylene chloride to corresponding epoxides. Effects of particle sizes, oxidation state, and location sites of Au nanoparticles, and epoxidation performance of Ti-containing materials. Delivering cutting-edge research and bridging the technology gap between fundamental research and industrial applications, Micro-Mesoporous Metallosilicates is a valuable resource for chemists, materials scientists, chemical engineers, and experienced researchers in related fields. Synthesis of Titanosilicates Layered Heteroatom-Containing Zeolites Synthesis and Catalytic Applications of Sn- and Zr-Zeolites Synthesis of Germanosilicates Structural Modifications on Germanosilicates Heteroatom-Containing Dendritic Mesoporous Silica Nanoparticles Chemical Post-Modifications of Titanosilicates Spectroscopic Characterization of Heteroatom-Containing Zeolites Theoretical Calculations of Heteroatom Substituted Zeolites Catalytic Ammoximation of Ketones or Aldehydes Using Titanosilicates Titanosilicate-Based Alkene Epoxidation Catalysis Propylene Epoxidation with Cumene Hydroperoxide/Titanosilicates Hydroxylation of Benzene and Phenol on Zeolite Catalysts Bifunctional Titanosilicate Systems for the Gas-Phase Catalytic Propylene Epoxidation with Hydrogen and Oxygen Zeolites Containing Heteroatoms/Metal Nanoparticles for Catalytic Conversion of Light Alkanes Design and Applications of Single-Site Photocatalysis Using Metallosilicates