Banerjee P. Donor Acceptor Cyclopropanes in Organic Synthesis 2024

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Banerjee P. Donor Acceptor Cyclopropanes in Organic Synthesis 2024

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Textbook in PDF format Facilitate milder, simpler reactions in organic synthesis with this cutting-edge family of building blocks. Donor-Accepted Cyclopropanes, or DACs, have attracted a resurgence of interest from organic chemists in recent decades for their role in facilitating various reactions such as cycloadditions, annulations, ring-opening and enantioselective transformations. The structural arrangement of DACs leads to milder, simpler reaction conditions, which have made them indispensable for a range of fundamentally and industrially important processes. Donor-Acceptor Cyclopropanes in Organic Synthesis covers comprehensively the chemistry and applications of this compound class. The result is an invaluable guide for any researcher looking to bring DACs to bear in their own areas of research or development. Readers will also find: A brief introduction of the history and reactivity of DACs. Detailed discussion of reactions including Lewis acid-catalyzed cycloadditions, metal-free activation, asymmetric transformations, organocatalysis, and many more. Application of DACs in natural product synthesis and pharmaceutical/agrochemical research. Donor-Acceptor Cyclopropanes in Organic Synthesis is ideal for organic chemists, experts in catalysis, pharmaceutical researchers, and any other scientists interested in facilitating milder, simpler reactions. Introduction to the Chemistry of Donor–Acceptor Cyclopropanes: A Historical and Personal Perspective Understanding the Reactivity of Donor–Acceptor Cyclopropanes: Structural and Electronic Analysis Cycloaddition and Annulation Reactions of Donor–Acceptor Cyclopropanes Activation of Donor–Acceptor Cyclopropanes under Covalent Organocatalysis: Enamine, Iminium, NHC, Phosphine and Tertiary Amine Catalysis Ring-Opening 1,3-Bisfunctionalization of Donor–Acceptor Cyclopropanes Molecular Rearrangements in Donor–Acceptor Cyclopropanes Donor–Acceptor Cyclopropanes with an Amino Group as Donor Reactivity of Cyclopropyl Monocarbonyls Chemistry of Aroyl- and Nitro-Substituted Donor–Acceptor Cyclopropanes Metal-Free Activation of the Donor–Acceptor Cyclopropanes: Protic Acids, Bases, and Thermal Reactions Asymmetric Catalytic Activation of Donor–Acceptor Cyclopropanes Application of Donor–Acceptor Cyclopropanes in Total Synthesis of Natural Products