Smith M. Organic Chemistry. An Acid-Base Approach 3ed 2023

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Smith M. Organic Chemistry. An Acid-Base Approach 3ed 2023

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Textbook in PDF format Based on the premise that many, if not most, reactions in organic chemistry can be explained by variations of fundamental acid–base concepts, Organic Chemistry: An Acid–Base Approach provides a framework for understanding the subject that goes beyond mere memorization. Using several techniques to develop a relational understanding, it helps students fully grasp the essential concepts at the root of organic chemistry.This new edition was rewritten largely with the feedback of students in mind and is also based on the author’s classroom experiences using the previous editions.The third edition of Organic Chemistry: An Acid–Base Approach constitutes a significant improvement upon a unique introductory technique to organic chemistry. The reactions and mechanisms it covers are the most fundamental concepts in organic chemistry that are applied to industry, biological chemistry, biochemistry, molecular biology, and pharmacy. Using an illustrated conceptual approach rather than presenting sets of principles and theories to memorize, it gives students a more concrete understanding of the material. Introduction Why Is an Acid–Base Theme Important? Bonding Alkanes, Isomers, and an Introduction to Nomenclature Functional Groups Acids, Bases, Nucleophiles, and Electrophiles Chemical Reactions, Bond Energy, and Kinetics Rotamers and Conformation Stereoisomers: Chirality, Enantiomers, and Diastereomers Acid–Base Reactions of pi-Bonds Nucleophiles: Lewis Base-Like Reactions at sp3 Carbon Base-Induced Elimination Reactions Substitution and Elimination Reactions Can Compete Spectroscopic Methods of Identification Organometallic Reagents Carbonyl Compounds: Structure, Nomenclature, Reactivity Oxidation Reactions of Aldehydes and Ketones Reduction Carboxylic Acid Derivatives and Acyl Substitution Aromatic Compounds and Benzene Derivatives Enolate Anions: Acyl Addition and Acyl Substitution Difunctional Molecules: Dienes and Conjugated Carbonyl Compounds Difunctional Molecules: Pericyclic Reactions Disconnections and Synthesis Heteroaromatic Compounds Multifunctional Compounds: Amines, Amino Acids and Peptides Multifunctional Compounds: Carbohydrates